Agronomic response, transpiration and water productivity of four almond production systems under different irrigation regimes
In recent years, more intensive production systems have been developed, coinciding with a growing scarcity of water resources. This context underscores the imperative of prioritizing water productivity (WP) as a critical factor in choosing the optimal production system to minimize agricultural water use. This study aims to contribute by evaluating WP in almond orchards under four production systems: open vase with severe pruning (open vase), open vase with minimal pruning (open vase (MP)), central axis and hedgerow. Three irrigation treatments were applied over two consecutive growing seasons: fully irrigated, mild stress and severe stress. Crop transpiration was monitored over the two years using both sap flow sensors and the two-source energy balance (TSEB) model with remote sensing. The severe stress treatment exhibited a notable reduction in kernel yield and nut load of 31.6 % and 34.5 %, respectively, in the second year of water deficit. The hedgerow system tended to have similar kernel yield to the open vase (MP) and central axis systems, and higher compared to the open vase system. Additionally, both transpiration measurement methods revealed that hedgerow exhibited lower transpiration rates across all irrigation treatments. Therefore, the highest WP was observed in the hedgerow system throughout both studied years. Similar findings were derived from the analysis of long-term data. Our findings indicate that the hedgerow production system had the highest WP, averaging 0.43 kg m−3 historically, compared to 0.33 kg m−3 for the open vase, 0.34 kg m−3 for the open vase (MP), and 0.36 kg m−3 for the central axis systems. https://doi.org/10.1016/j.scienta.2024.113335
Extraction of bioactive compounds from pecan nutshell: An added-value and low-cost alternative for an industrial waste
The pecan nutshell [Carya illinoinensis (Wangenh) C. Koch] (PNS) is a source of bioactives with important beneficial properties for the human health. PNS represents between 40-50 % of total mass of the nut, resulting as waste without any added value for the food industry. Even though a variety of methods were already developed for bioactive extraction from this waste, unconventional methodologies, or those which apart from green chemistry principles, were discarded considering the cost of production, the sustainable development goals of United Nations and the feasibility of real inclusion of the technology in the food chain. Then, to add-value to this waste, a low-cost, green and easy-scalable extraction methodology was developed based on the determination of seven relevant factors by means of a factorial design and a Response Surface Methodology, allowing the extraction of bioactives with antioxidant capacity. The pecan nutshell extract had a high concentration of phenolic compounds (166 mg gallic acid equivalents-GAE/g dry weight-dw), flavonoids (90 mg catechin equivalent-CE/g dw) and condensed tannins (189 mg CE/g dw) -related also to the polymeric color (74.6 %)-, with high antioxidant capacities of ABTS+. radical inhibition (3665 µmol Trolox Equivalent-TE/g dw) and of iron reduction (1305 µmol TE/g dw). Several compounds associated with these determinations were identified by HPLC-ESI-MS/MS, such as [Epi]catechin-[Epi]catechin-[Epi]gallocatechin, myricetin, dihydroquercetins, dimers A and B of protoanthocyanidins, ellagitannins and ellagic acid derivatives. Hence, through the methodology developed here, we obtained a phenolic rich extract with possible benefits for human health, and of high industrial scalability for this co-product transformation. https://doi.org/10.1016/j.foodchem.2024.139596
Green and sustainable use of macadamia nuts as support material in Pt-based direct methanol fuel cells
The successful commercialization of direct methanol fuel cells (DMFCs) is hindered by inadequate methanol oxidation activity and anode catalyst longevity. Efficient and cost-effective electrode materials are imperative in the widespread use of DMFCs. While Platinum (Pt) remains the primary component of anodic methanol oxidation reaction (MOR) electrocatalysts, its utilization alone in DMFC systems is limited due to carbon monoxide (CO) poisoning, instability, methanol crossover, and high cost. These limitations impede the economic feasibility of Pt as an electrocatalyst. Herein, we present the use of powdered activated carbon (PAC) and granular activated carbon (GAC), both sourced from macadamia nut shells (MNS), a type of biomass. These bio-based carbon materials are integrated into hybrid supports with reduced graphene oxide (rGO), aiming to enhance the performance and reduce the production cost of the Pt electrocatalyst. Electrochemical and physicochemical characterizations of the synthesized catalysts, including Pt-rGO/PAC-1:1, Pt-rGO/PAC-1:2, Pt-rGO/GAC-1:1, and Pt-rGO/GAC-1:2, were conducted. X-ray diffraction analysis revealed crystallite sizes ranging from 1.18 nm to 1.68 nm. High-resolution transmission electron microscopy (HRTEM) images with average particle sizes ranging from 1.91 nm to 2.72 nm demonstrated spherical dispersion of Pt nanoparticles with some agglomeration across all catalysts. The electrochemical active surface area (ECSA) was determined, with Pt-rGO/GAC-1:1 exhibiting the highest ECSA of 73.53 m2 g-1. Despite its high ECSA, Pt-rGO/GAC-1:1 displayed the lowest methanol oxidation reaction (MOR) current density, indicating active sites with poor catalytic efficiency. Pt-rGO/PAC-1:1 and Pt-rGO/PAC-1:2 exhibited the highest MOR current densities of 0.77 mA*cm-2 and 0.74 mA*cm-2, respectively. Moreover, Pt-rGO/PAC-1:2 and Pt-rGO/PAC-1:1 demonstrated superior electrocatalytic mass (specific) activities of 7.55 mA/mg (0.025 mA*cm-2) and 7.25 mA/mg (0.021 mA*cm-2), respectively. Chronoamperometry tests revealed Pt-rGO/PAC-1:2 and Pt-rGO/PAC-1:1 as the most stable catalysts. Additionally, they exhibited the lowest charge transfer resistances and highest MOR current densities after durability tests, highlighting their potential for DMFC applications. The synthesized Pt supported on PACs hybrids demonstrated remarkable catalytic performance, stability, and CO tolerance, highlighting their potential for enhancing DMFC efficiency. https://doi.org/10.1016/j.heliyon.2024.e29907
Predictive Neural Network Modeling for Almond Harvest Dust Control
This study introduces a neural network-based approach to predict dust emissions, specifically PM2.5 particles, during almond harvesting in California. Using a feedforward neural network (FNN), this research predicted PM2.5 emissions by analyzing key operational parameters of an advanced almond harvester. Preprocessing steps like outlier removal and normalization were employed to refine the dataset for training. The network's architecture was designed with two hidden layers and optimized using tanh activation and MSE loss functions through the Adam algorithm, striking a balance between model complexity and predictive accuracy. The model was trained on extensive field data from an almond pickup system, including variables like brush speed, angular velocity, and harvester forward speed. The results demonstrate a notable predictive accuracy of the FNN model, with a mean squared error (MSE) of 0.02 and a mean absolute error (MAE) of 0.01, indicating high precision in forecasting PM2.5 levels. By integrating machine learning with agricultural practices, this research provides a significant tool for environmental management in almond production, offering a method to reduce harmful emissions while maintaining operational efficiency. This model presents a solution for the almond industry and sets a precedent for applying predictive analytics in sustainable agriculture. https://doi.org/10.3390/s24072136
A review to frame the utilization of Eastern black walnut (Juglans nigra L.) cultivars in alley cropping systems
Agroforestry adoptition is gaining considerable traction in the temperate US with growing popularity and government incentives (e.g., the Partnerships for Climate-Smart Commodities Project) for systems with greenhouse gas mitigation potential. The identification of complementary species combinations will accelerate the expansion of temperate agroforestry. Since the mid-19th century, European timber plantations have taken advantage of the late-leafing habit of walnut (Juglans spp.) to grow a spring grain crop between the tree rows. Such alley cropping systems increase land-use efficiency and provide extensive environmental benefits. A parallel but underutilized opportunity in North American involves incorporating eastern black walnut (Juglans nigra L.) cultivars into alley cropping systems (ACS). Eastern black walnut, henceforth referred to as black walnut, is native to North America and exhibits architectural and phenological characters for reduced competition with winter cereal crops grown in alleys. Black walnut also produces nutritious nuts, and cultivars with improved kernel percentage and mass offer potential to cultivate the species as a domesticated orchard crop, as opposed to just the high-quality timber for which it is well-known. However, field observations suggest significant variation in tree architecture and phenology amongst cultivars, which is likely to influence complementarity with winter grains. Comprehensive characterization of trait genetic diversity is needed to best leverage germplasm into productive systems. Here, we review literature related to implementing ACS with consideration of cultivar-dependent traits that may reduce interspecific competition. While the focus is directed toward black walnut, broad characterization of other underutilized fruit/nut species will allow for robust diversification of ACS.
https://doi.org/10.1007/s10457-023-00909-0
Large-scale assessment of date palm plantations based on UAV remote sensing and multiscale vision transformer
Timely and efficient mapping of date palm plantations through unmanned aerial vehicle (UAV) remote sensing is critical for continuous observation, health and risk evaluation, pest management, resource optimization, and ensuring the long-term sustainability of the dates industry. This study presents an efficient and cost-effective transformer-based approach to identify, countify, monitor, and evaluate the overall well-being of palm trees using extensive UAV imagery. The suggested approach integrates an improved multiscale vision transformer, feature pyramid network, Mask R–CNN, and improved slicing-aided hyper inference for practical large-scale assessments. This combination enabled the extraction of multiscale features, capturing long-range dependencies in the data and boosting the model's generalizability. The proposed architecture outperformed several CNN-based architectures (including Mask R–CNN, Cascade Mask R–CNN, Point-based Rendering, and You Only Look At CoefficientTs), achieving F-scores of 94.33% and 94.2% for date palm tree detection and segmentation, respectively. The transformer-based architecture was optimized using transfer learning to differentiate between healthy and unhealthy date palm trees, particularly those with severe infestations. The potential generic condition of date palm trees was predicted with an F-score of 88.4%. Further advancements in this field could pave the way for a proactive strategy, enabling timely detection, which would aid in pest management and support the sustainable growth of the dates sector.
https://doi.org/10.1016/j.rsase.2024.101195
Alternative fertilization practices lead to improvements in yield-scaled global warming potential in almond orchards
This study investigates the impact of alternative fertilization practices on the yield-scaled global warming potential (YS-GWP) in almond orchards. Almond production is a contributor to greenhouse gas emissions, primarily due to nitrogen-based mineral fertilizers. This research aims to identify strategies that reduce the environmental footprint of almond cultivation while maintaining yield. Field experiments were conducted in an almond orchard using three alternative fertigation practices: Advance Grower Practice (AGP), Pump and Fertilize (P&F), and High Frequency Low Concentration (HFLC). AGP is the current practice used by producers to meet annual N demand for almond tree growth; P&F is a reduction in applied N rate in response to measured N concentrations in the groundwater so that the added N and groundwater N reach the same total N applied; HFLC is a practice of applying smaller N rates per individual event. HFLC uses a greater number of fertigation events to reach similar total annual N load as other treatments. Cumulative N2O and CH4 emissions were used to determine GWP by converting the emissions to carbon dioxide equivalents (CO2eq) within a 100-year horizon. Nitrous oxide emissions were multiplied by a radiative forcing potential CO2eq of 298 and CH4 by 25 (UNFCCC, 2007). The results revealed that both P&F and HFLC reduced the YS-GWP compared to AGP. HFLC demonstrated 52–78% decrease in GWP per unit of almond yield compared to AGP, while P&F showed 48–58% decrease over AGP. These reductions were attributed to the reduced nitrous oxide emissions associated with P&F and HFLC. Further, P&F and HFLC tended to have higher N use efficiency than AGP. We demonstrate that adopting alternative fertilization practices can effectively mitigate the environmental footprint of almond orchards while maintaining crop yields. These practices offer viable options for almond growers to reduce greenhouse gas emissions, enhance sustainability, and contribute to climate change mitigation.
https://doi.org/10.1016/j.agee.2023.108857
Pickering emulsions stabilized by cellulose nanocrystals extracted from hazelnut shells: Production and stability under different harsh conditions
Cellulose nanocrystals (CNCs) are biodegradable particles that have emerged as promising stabilizers for Pickering emulsions. This study investigated the effectiveness of CNCs in forming the Pickering emulsion from hazelnut shells (HS), an agricultural waste. Following the alkaline and bleaching treatments applied to HS, CNCs were obtained from treated hazelnut shell with acid hydrolysis. The physicochemical characteristics of CNCs were investigated using dynamic light scattering, XRD, FTIR, SEM, and TEM. A high crystalline (69.6 %) CNCs with a spherical shape were obtained. Contact angle and interfacial tension tests were conducted and showed that CNCs had amphiphilic nature. Pickering emulsions were investigated for their size, zeta potential, and stability under varying CNC concentrations. The results showed that when CNCs concentration increased from 0.5 to 2.0 wt%, droplet diameter decreased approximately 1.8 times and zeta potential increased. Creaming was not observed during 28 days of storage in a concentration of 2.0 wt% CNCs. The CNC stabilized emulsions exhibited high stability within a range of pH, temperatures, and salt concentrations. This study demonstrated that CNCs extracted from HS as environmentally friendly and cost-effective materials, could serve as a new stabilizer for Pickering emulsions especially for high temperature and low pH sensitive products such as mayonnaise.
https://doi.org/10.1016/j.ijbiomac.2023.128982
Nut bush pesticide limits: urgent need for a comprehensive strategy to address current and emerging insect pests and insecticide options in the Australian macadamia industry
In Australia, macadamia orchards are attacked by four main insect pest groups. Management and control of three of these key pests currently relies on broad-spectrum insecticides whose long-term future is questionable. Of the 23 insecticides registered for use in macadamia in Australia, 19 face issues affecting their availability and 12 are presently not approved in the EU, the USA or Canada. These international markets may refuse produce that does not adhere to their own insecticide use standards, hence Australian produce may be excluded from market access. Many of the potential replacement integrated pest management methods of pest control are generally considered less effective by the industry and have not been adopted. There are 17 insect pest groups identified by the industry, any of which have potential to become major problems if broad-spectrum insecticide options become unavailable. Thirteen pest groups need urgent attention as they are at risk of losing current effective control methods, and no replacement solutions have yet been developed. The lag period for research and development to identify new chemical and biological control solutions means there is now an urgent need for the macadamia industry to craft a strategy for sustainable pest management for each pest. Critically, this industry strategy needs to address the vulnerabilities identified in this paper, identify potential solutions for any cases of market failure and consider funding mechanisms to address these gaps. On economic and sustainability grounds, potential biological control options should be explored, especially in cases where insecticide control options are vulnerable.
https://doi.org/10.1002/ps.8043
Fe2O3/carbon derived from peanut shell hybrid as an advanced anode for high performance lithium ion batteries
Carbon materials derived from biomass behave sustainability, easy availability, low cost and environmentally benign. And Fe2O3 are considered as promising anodes for high-performance Li-ion batteries (LIBs) because of their rich electrochemical properties, higher theoretical capacity (1007 mAh g−1), non-toxicity, high corrosion resistance and safety. However, the high irreversible capacity loss and poor cycling stability of Fe2O3 hinders its commercial applications in LIBs. In this work, we have developed a Fe2O3@C derived from peanut shell composite by two-step hydrothermal method and low-temperature calcination with the assistance of Fe(NO3)3. As an anode for LIBs, the Fe2O3@C composite an excellent electrochemical performance in term of the specific capacity of 1000.8 mAh g−1 at 200 mA g−1 after 100 cycles, and high rate capability of 573.5 mAh g−1 even at 1 A g−1 after 200 cycles. This enhancement could be attributed to the porous carbon matrix combined with Fe2O3 nanoparticles which could increase contact area between electrolyte and active materials, improve conductivity, and accommodate the volume variations via additional void space during cycling. This work may be provide a new approach to improve anode materials using carbon derived-from biomass with larger reversible capacity and long cycle life in LIBs.
https://doi.org/10.1016/j.est.2023.107731